Activation of Hydrogen Peroxide by Iron-Containing Minerals and Catalysts in. Financial Constraints. Dehydrogenation of Light Alkanes over Supported Pt. Incentives in Baseball. Enzymatic Baeyer-Villiger Oxidation for Natural Product Synthesis. Prospects And Implications. How to document and maintain a Quality System. During glacial intervals, such as the Pongola at ca 2.9 Gyr ago and the Huronian at ca 2.5–2.3 Gyr ago, H2O2 would accumulate in ice and be released in the basal meltwaters. O2 released by H2O2 disproportionation could then act as a local agent for oxic poisoning and drive the evolution of oxygen-mediating enzymes.
Hans- Zimmer. Thank you so much for your inspiring links on You. Tube about your Master Class. Anaerobic degradation of alkanes. Initial activation of the alkane (in black) occurs by addition of a fumarate molecule (in grey), which is later regenerated., Enhanced enzymatic and ex situ biodegradation of petroleum hydrocarbons in solutions using Alcanivorax borkumensis enzymes in the presence of nitrogen and phosphorus co-doped. Enzymes with hydroxylating activity on alkanes have potential application as biotransformation catalysts in chemical and pharmaceutical industry. Genome of Alcanivorax borkumensis, a marine bacterium with hydrocarbon dissimilation activity, contains at least two P450 monooxygenases and two nonheme monooxygenases, AlkB1 and AlkB2, respectively. Department of Chemistry & QOPNA—Organic Chemistry, Natural Products and Food Stuffs, University of Aveiro, Campus de Santiago, 3810-193 Aveiro, Portugal. Six years later, Alexander Fleming (United Kingdom), Ernst Chain (Germany/United Kingdom), and Howard Florey (Australia/United Kingdom) shared the prize for the discovery of penicillin. Of the three, Fleming (1881–1955) is best known. The story how he discovered this antibiotic has been told many times.
Abels, C.; Carstensen, F.; Wessling, M.
Methane partial oxidation by unsupported and silica supported iron phosphate catalysts—influence of reaction conditions and co-feeding of water on activity and selectivity
Alptekin, G.O.; Herring, A.M.; Williamson, D.L.; Ohno, T.R.; McCormick, R.L.
Anthony, C.
Selective hydroxylation of benzene derivatives and alkanes with hydrogen peroxide catalysed by a manganese complex incorporated into mesoporous silica-alumina
Cofactor-independent oxygenation reactions catalyzed by soluble methane monooxygenase at the surface of a modified gold electrode
Astier, Y.; Balendra, S.; Hill, H.A.O.; Smith, T.J.; Dalton, H.
Enzymatic activation of alkanes: constraints and prospective
Mild, aqueous, aerobic, catalytic oxidation of methane to methanol and acetaldehyde catalyzed by a supported bipyrimidinylplatinum-polyoxometalate hybrid compound
Elucidating membrane surface properties for preventing fouling of bioreactor membranes by surfactin
Behary, N.; Lecouturier, D.; Perwuelz, A.; Dhulster, P.
Direct oxidation of methane to oxygenates over heteropolyanions
Benlounes, O.; Mansouri, S.; Rabia, C.; Hocine, S.
Structure and catalytic properties of VOx/MCM materials for the partial oxidation of methane to formaldehyde
Berndt, H.; Martin, A.; Bruckner, A.; Schreier, E.; Muller, D.; Kosslick, H.; Wolf, G.U.; Lucke, B.
Production of primary aliphatic-alcohols with a recombinant Pseudomonas strain, encoding the alkane hydroxylase enzyme-system
Bosetti, A.; van Beilen, J.B.; Preusting, H.; Lageveen, R.G.; Witholt, B.
The methanotrophs − the families methylococcaceae and methylocystaceeae
Bacterial dry matter content and biomass estimations
Methane as raw material in synthetic chemistry: the final frontier
Utilizing terminal oxidants to achieve P450-Catalyzed oxidation of methane
Directed Evolution of Cytochrome P450 for Small Alkane Hydroxylation. Thesis
Oxygen transfer in hydrocarbon-aqueous dispersions and its applicability to alkane bioprocesses: a review
Envisioning the bioconversion of methane to liquid fuels
Kinetic characterization of the soluble butane monooxygenase from Thauera butanivorans, formerly ‘ Pseudomonas butanovora ’
Cooley, R.B.; Dubbel, B.L.; Sayavedra-Soto, L.A.; Bottomley, P.J.; Arp, D.J.
Green oxidation of fatty alcohols: challenges and opportunities
Cortes Corberan, V.; Gonzalez-Perez, M.E.; Martinez-Gonzalez, S.; Gomez-Aviles, A.
High-rate conversion of methane to methanol by Methylosinus trichosporium OB3b
Butane monooxygenase of ‘ Pseudomonas butanovora ': purification and biochemical characterization of a terminal-alkane hydroxylating diiron monooxygenase
Regio- and stereoselectivity of particulate methane monooxygenase from Methylococcus capsulatus (Bath)
Elliott, S.J.; Zhu, M.; Tso, L.; Nguyen, H.H.T.; Yip, J.H.K.; Chan, S.I.
Enzymatic synthesis of butyl acetate in a packed bed reactor underliquid and supercritical conditions
Escandell, J.; Wurm, D.J.; Belleville, M.-P.; Sanchez, J.; Harasek, M.; Paolucci-Jeanjean, D.
Engineered alkane-hydroxylating cytochrome P450(BM3) exhibiting nativelike catalytic properties
Direct catalytic-oxidation of methane to methanol—a review
Production of α,(-Alkanediols using Escherichia coli expressing a cytochrome p450 from Acinetobacter sp. OC4
Fujii, T.; Narikawa, T.; Sumisa, F.; Arisawa, A.; Takeda, K.; Kato, J.
Application of a continuously stirred tank bioreactor (CSTR) for bioremediation of hydrocarbon-rich industrial wastewater effluents
Gargouri, B.; Karray, F.; Mhiri, N.; Aloui, F.; Sayadi, S.
Biological conversion of methane to liquid fuels: status and opportunities
Laboratory evolution of a soluble, self-sufficient, highly active alkane hydroxylase
Catalyst-controlled aliphatic C–H oxidations with a predictive model for site-selectivity
Whole-cell bio-oxidation of n-dodecane using the alkane hydroxylase system of P-putida GPo1 expressed in E-coil
Substrate-specificity of soluble methane monooxygenase − mechanistic implications
Selective oxidation of methane by the bis(mu-oxo) dicopper core stabilized on ZSM-5 and mordenite zeolites
Groothaert, M.H.; Smeets, P.J.; Sels, B.F.; Jacobs, P.A.; Schoonheydt, R.A.
Engineered catalytic biofilms for continuous large scale production of n-octanol and ( S )-styrene oxide
Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol
Grundner, S.; Markovits, M.A.C.; Li, G.; Tromp, M.; Pidko, E.A.; Hensen, E.J.M.; Jentys, A.; Sanchez-Sanchez, M.; Lercher, J.A.
Hanson, R.S.; Hanson, T.E.
Methane partial oxidation to methanol over Ga2O3 based catalysts: use of the CH4 /D2 exchange reaction as a design tool
Hargreaves, J.S.J.; Hutchings, G.J.; Joyner, R.W.; Taylor, S.H.
Non-enzymatic regeneration of nicotinamide and flavin cofactors for monooxygenase catalysis
Separation of methanol from methanol/water mixtures with pervaporation hybrid membranes
A review of separation technologies in current and future biorefineries
Huang, H.J.; Ramaswamy, S.; Tschirner, U.W.; Ramarao, B.V.
Strategies for regeneration of nicotinamide coenzymes emphasizing self-sufficient closed-loop recycling systems
Biocatalytic conversion of methane to methanol as a key step for development of methane-Based biorefineries
Hwang, I.Y.; Lee, S.H.; Choi, Y.S.; Park, S.J.; Na, J.G.; Chang, I.S.; Kim, C.; Kim, H.C.; Kim, Y.H.; Lee, J.W.; Lee, E.Y.
Methane oxidation at 55 degrees C and pH 2 by a thermoacidophilic bacterium belonging to the Verrucomicrobia phylum
Islam, T.; Jensen, S.; Reigstad, L.J.; Larsen, O.; Birkeland, N.K.
Methane hydroxylation using light energy by the combination of thylakoid and methane monooxygenase
Ito, H.; Mori, F.; Tabata, K.; Okura, I.; Kamachi, T.
Activation of the hydroxylase of sMMO from Methylococcus-capsulatus (Bath) by hydrogen-peroxide
Selective oxidation of methane to methanol catalyzed, with CH activation, by homogeneous, cationic gold
Jones, C.J.; Taube, D.; Ziatdinov, V.R.; Periana, R.A.; Nielsen, R.J.; Oxgaard, J.; Goddard, W.A.
Enzyme Catalysis in an Aqueous/Organic Segment Flow Microreactor: Ways to Stabilize Enzyme Activity
Use of perfluorocarboxylic acids to trick cytochrome p450bm3 into initiating the hydroxylation of gaseous alkanes
Direct hydroxylation of primary carbons in small alkanes by wild-type cytochrome P450 BM3 containing perfluorocarboxylic acids as decoy molecules
Selective oxidation of methane by molecular oxygen catalyzed by a bridged binuclear ruthenium complex at moderate pressures and ambient temperature
Kim, J.; Grate, J.W.; Wang, P.
Regeneration of the nicotinamide cofactor using a mediator-free electrochemical method with a tin oxide electrode
Optimization of lab scale methanol production by Methylosinus trichosporium OB3b
Partial oxidation of methane over silica catalysts promoted by 3D transition-metal ions
Kobayashi, T.; Nakagawa, K.; Tabata, K.; Haruta, M.
In vivo evolution of butane oxidation by terminal alkane hydroxylases AlkB and CYP153A6
Koch, D.J.; Chen, M.M.; van Beilen, J.B.; Arnold, F.H.
Pervaporative removal of organics from water using hydrophobic membranes Binary mixtures
Novel dual extraction process for acetone-butanol-ethanol fermentation
Petroleum-contaminated water treatment in a fluidized-bed bioreactor with immobilized Rhodococcus cells
Kuyukina, M.S.; Ivshina, I.B.; Serebrennikova, M.K.; Krivorutchko, A.B.; Podorozhko, E.A.; Ivanov, R.V.; Lozinsky, V.I.
Catalytic oxygenation of organic substrates: toward greener ways for incorporating oxygen
H 2 -driven cofactor regeneration with NAD(P)+-reducing hydrogenases
Efficient and selective formation of methanol from methane in a fuel cell-type reactor
Coenzyme analogs: excellent substitutes (not poor imitations) for electrochemical regeneration
Selective oxidation of methane and its homologues to alcohols catalyzed by gold compounds and a proposed reaction mechanism
Levchenko, L.A.; Lobanova, N.G.; Martynenko, V.M.; Sadkov, A.P.; Shestakov, A.F.; Shilova, A.K.; Shilov, A.E.
Biological methane oxidation: Regulation, biochemistry, and active site structure of particulate methane monooxygenase
Rhodococcus erythropolis strain NTU-1 efficiently degrades and traps diesel and crude oil in batch and fed-batch bioreactors
Towards continuous sustainable processes for enzymatic synthesis of biodiesel in hydrophobic ionic liquids/supercritical carbon dioxide biphasic systems
Halogenated metalloporphorin complexes as catalysts for selective reactions of acyclic alkanes with molecular oxygen
Integrated two-liquid phase bioconversion and product-recovery processes for the oxidation of alkanes: process design and economic evaluation
Microbial communities involved in anaerobic degradation of alkanes
Mbadinga, S.M.; Wang, L.Y.; Zhou, L.; Liu, J.F.; Gu, J.D.; Mu, B.Z.
Methanol biosynthesis by covalently immobilized cells of Methylosinus trichosporium : batch and continuous studies
Direct conversion of ethane to ethanol by engineered cytochrome P450BM3
Meinhold, P.; Peters, M.W.; Chen, M.M.Y.; Takahashi, K.; Arnold, F.H.
Hydrogen peroxide as an effecter on the inactivation of particulate methane monooxygenase under aerobic conditions
Miyaji, A.; Suzuki, M.; Baba, T.; Kamachi, T.; Okura, I.
The P450 Superfamily: Updated Listing of All Genes and Recommended Nomenclature for the chromosomal Loci
Nebert, D.W.; Nelson, D.R.; Adesnik, M.; Coon, M.J.; Estabrook, R.W.; Gonzalez, F.J.; Guengerich, F.P.; Gunsalus, I.C.; Johnson, E.F.; Kemper, B.; Levin, W.; Phillips, I.R.; Sato, R.; Waterman, M.R.
The P450 superfamily: update on new sequences, gene-mapping, and recommended nomenclature
Nebert, D.W.; Nelson, D.R.; Coon, M.J.; Estabrook, R.W.; Feyereisen, R.; Fujiikuriyama, Y.; Gonzalez, F.J.; Guengerich, F.P.; Gunsalus, I.C.; Johnson, E.F.; Loper, J.C.; Sato, R.; Waterman, M.R.; Waxman, D.J.
The P450 Superfamily: update on new sequences, gene-mapping, accession numbers, early trivial names of enzymes, and nomenclature
Nelson, D.R.; Kamataki, T.; Waxman, D.J.; Guengerich, F.P.; Estabrook, R.W.; Feyereisen, R.; Gonzalez, F.J.; Coon, M.J.; Gunsalus, I.C.; Gotoh, O.; Okuda, K.; Nebert, D.W.
P450 superfamily: update on new sequences, gene mapping, accession numbers and nomenclature
Nelson, D.R.; Koymans, L.; Kamataki, T.; Stegeman, J.J.; Feyereisen, R.; Waxman, D.J.; Waterman, M.R.; Gotoh, O.; Coon, M.J.; Estabrook, R.W.; Gunsalus, I.C.; Nebert, D.W.
Biodegradation pattern of hydrocarbons from a fuel oil-type complex residue by an emulsifier-producing microbial consortium
Nievas, M.L.; Commendatore, M.G.; Esteves, J.L.; Bucala, V.
Functional expression system for cytochrome P450 genes using the reductase domain of self-sufficient P450RhF from Rhodococcus sp NCIMB 9784
Regio- and stereoselective subterminal hydroxylations of n-Decane by fungi in a liquid-Liquid interface bioreactor (L–L IBR)
Enhancement of biodegradation of oil adsorbed on fine soils in a bioslurry reactor
Okuda, T.; Alcantara-Garduno, M.E.; Suzuki, M.; Matsui, C.; Kose, T.; Nishijima, W.; Okada, M.
Park, D.H.; Lee, J.
Microbial oxidation of hydrocarbons: properties of a soluble methane monooxygenase from a facultative methane-utilizing organism, Methylobacterium sp. Strain CRL-26
Butane oxidation process development in a circulating fluidized bed
A mercury-catalyzed, high-yield system for the oxidation of methane to methanol
Periana, R.A.; Taube, D.J.; Evitt, E.R.; Loffler, D.G.; Wentrcek, P.R.; Voss, G.; Masuda, T.
Evolving P450pyr hydroxylase for highly enantioselective hydroxylation at non-activated carbon atom
Pham, S.Q.; Pompidor, G.; Liu, J.; Li, X.D.; Li, Z.
Engineering of recombinant E. coli cells co-expressing P450pyrTM monooxygenase and glucose dehydrogenase for highly regio- and stereoselective hydroxylation of alicycles with cofactor recycling
Identification of novel methane-, ethane-, and propane-oxidizing bacteria at marine hydrocarbon seeps by stable isotope probing
Analysis of methane biodegradation by Methylosinus trichosporium OB3b
Selective catalytic oxidation of CH bonds with molecular oxygen
Roduner, E.; Kaim, W.; Sarkar, B.; Urlacher, V.B.; Pleiss, J.; Glaser, R.; Einicke, W.D.; Sprenger, G.A.; Beifuß, U.; Klemm, E.; Liebner, C.; Hieronymus, H.; Hsu, S.F.; Plietker, B.; Laschat, S.
Synthesis, molecular structure, and catalytic potential of the tetrairon complex Fe 4 (N 3 O 2 -L)( 4 )(μ-O)( 2 ) ( 4+ ) (L=1-carboxymethyl-4,7-dimethyl-1,4,7-triazacyclononane)
Romakh, V.B.; Therrien, B.; Suss-Fink, G.; Shul'pin, G.B.
P450cam biocatalysis in surfactant-stabilized two-phase emulsions
Regioselective -hydroxylation of medium-chain n-alkanes and primary alcohols by CYP153 enzymes from Mycobacterium marinum and Polaromonas sp strain JS666
Scheps, D.; Malca, S.H.; Hoffmann, H.; Nestl, B.M.; Hauer, B.
Whole-cell biocatalysis for selective and productive CO functional group introduction and modification
Schrewe, M.; Julsing, M.K.; Buhler, B.; Schmid, A.
Semrau, J.D.; Dispirito, A.A.; Yoon, S.
Mossbauer studies of alkane omega-hydroxylase: evidence for a diiron cluster in an integral-membrane enzyme
Shanklin, J.; Achim, C.; Schmidt, H.; Fox, B.G.; Munck, E.
Distribution and diversity of Verrucomicrobia methanotrophs in geothermal and acidic environments
Sharp, C.E.; Smirnova, A.V.; Graham, J.M.; Stott, M.B.; Khadka, R.; Moore, T.R.; Grasby, S.E.; Strack, M.; Dunfield, P.F.
Anaerobic oxidation of methane and its homologues in the presence of gold compounds
Shestakov, A.F.; Shilova, A.K.; Sadkov, A.P.; Lariontseva, N.V.; Golovanova, S.A.; Levchenko, L.A.; Shilov, A.E.
Direct conversion of methane to methanol and formaldehyde over a double-layered catalyst bed in the presence of steam
Shi, C.L.; Sun, Q.; Hu, H.C.; Herman, R.G.; Klier, K.; Wachs, I.E.
Recent progress in oxidation of n-alkanes by heterogeneous catalysis
Sivaramakrishna, A.; Suman, P.; Goud, E.V.; Janardan, S.; Sravani, C.; Yadav, C.S.; Clayton, H.S.
Smith, T.J.; Murrell, J.C.
Oxidation of methane and ethylene in water at ambient conditions
Sorokin, A.B.; Kudrik, E.V.; Alvarez, L.X.; Afanasiev, P.; Millet, J.M.M.; Bouchu, D.
Electrochemical reduction of CO 2 catalysed by Geobacter sulfurreducens grown on polarized stainless steel cathodes
Soussan, L.; Riess, J.; Erable, B.; Delia, M.L.; Bergel, A.
Biocatalytic hydroxylation of n-butane with in situ cofactor regeneration at low temperature and under normal pressure
Staudt, S.; Mueller, C.A.; Marienhagen, J.; Boeing, C.; Buchholz, S.; Schwaneberg, U.; Groeger, H.
Biocatalytic methanol production from methane with Methylosinus trichosporium OB3b: an approach to improve methanol accumulation
CYP63A2, a catalytically versatile fungal P450 monooxygenase capable of oxidizing higher-molecular-weight polycyclic aromatic hydrocarbons, alkylphenols, and alkanes
Syed, K.; Porollo, A.; Lam, Y.W.; Grimmett, P.E.; Yadav, J.S.
Hydrogen and methanol formation utilizing bioprocesses
The partial oxidation of methane to methanol: an approach to catalyst design
Taylor, S.H.; Hargreaves, J.S.J.; Hutchings, G.J.; Joyner, R.W.; Lembacher, C.W.
Dioxygen activation in soluble methane monooxygenase
First structural-functional model of methane monooxygenase
Trukhan, V.M.; Polukhov, V.V.; Sulimenkov, I.V.; Ovanesyan, N.S.; Koval'chuk, N.A.; Dodonov, A.F.; Shteinman, A.A.
Cofactor regeneration—an important aspect of biocatalysis
Production of 1-Octanol from n-Octane by Pseudomonas putida KT2440
Vallon, T.; Glemser, M.; Malca, S.H.; Scheps, D.; Schmid, J.; Siemann-Herzberg, M.; Hauer, B.; Takors, R.
Effect of membrane and process characteristics on cost and energy usage for separating alcohol-water mixtures using a hybrid vapor stripping-vapor permeation process
A review of pervaporation for product recovery from biomass fermentation processes
Partial oxidation of methane to methanol − Comparison of heterogeneous catalyst and homogeneous gas-phase reactions
Partial oxidation of methane on Mo/Sn/P silica supported catalysts
Enrichment, Isolation and some properties of methane-utilizing bacteria
Production of methanol from methane by methanotrophic bacteria
Xin, J.Y.; Cui, J.R.; Niu, J.Z.; Hua, S.F.; Xia, C.G.; Li, S.B.; Zhu, L.M.
Engineering of P450pyr hydroxylase for the highly regio- and enantioselective subterminal hydroxylation of alkanes
First steps towards a Zn/Co(III) sep-driven P450 BM3 reactor
Expanding the alkane oxygenase toolbox: new enzymes and applications
Alkane hydroxylases involved in microbial alkane degradation
Substrate specificity of the alkane hydroxylase system of Pseudomonas oleovorans GPo1
Zilly, F.E.; Acevedo, J.P.; Augustyniak, W.; Deege, A.; Haeusig, U.W.; Reetz, M.T.